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Beilstein J. Org. Chem. 2013, 9, 2635–2640, doi:10.3762/bjoc.9.299
Graphical Abstract
Scheme 1: Construction of the Cvinyl–CF3 bond.
Scheme 2: Proposed reaction paths for the trifluoromethylation of alkenes.
Figure 1: Cu(I)-catalyzed trifluoromethylation of terminal alkenes with Togni’s reagent. Isolated yield are r...
Scheme 3: Proposed mechanism for the trifluoromethylation of terminal alkenes.